Cold crucible induction melter test for crystalline ceramic waste form fabrication: A feasibility assessment

Vitrification of Hlw Produced by Uranium/molybdenum Fuel Reprocessing in Cogema’s Cold Crucible Melter

The performance of the vitrification process currently used in the La Hague commercial reprocessing plants has been continuously improved during more than ten years of operation. In parallel COGEMA (industrial Operator), the French Atomic Energy Commission (CEA) and SGN (respectively COGEMA’s R&D provider and Engineering) have developed the cold crucible melter vitrification technology to obtai...

Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification

In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass-forming and modifying additives) experiences multiple gas-evolving reactions in an electrical glass-melting furnace. We employed the thermogravimetry-gas chromatography–mass spectrometry (TGA-GC–MS) combination to perform evolved gas analysis (EGA). Along with identifying the gases evolved, we performe...

Ceramic Package Fabrication for YMP Nuclear Waste Disposal

Evolution of Continuous Melting and Decontamination Technology for Dismantled Metal by an Induction Cold Crucible

An induction cold crucible melting is one of the most promising technologies for the reuse and decontamination of the radioactively contaminated metallic materials generated during the dismantling of nuclear facilities, because the crucible ensures a long life operation without generating secondary wastes. Fundamental equipment of the Melting and Recycling of Metals by Cold Crucible (MERC) proc...

A-site compositional effects in Ga-doped hollandite materials of the form BaxCsyGa2x+yTi8−2x−yO16: implications for Cs immobilization in crystalline ceramic waste forms

The hollandite structure is a promising crystalline host for Cs immobilization. A series of Ga-doped hollandite BaxCsyGa2x+yTi8-2x-yO16 (x = 0, 0.667, 1.04, 1.33; y = 1.33, 0.667, 0.24, 0) was synthesized through a solid oxide reaction method resulting in a tetragonal hollandite structure (space group I4/m). The lattice parameter associated with the tunnel dimension was found to increases as Cs...